This option is usually only to be recommended if you are dealing with a new installation and no posts, since the Permalinks for your old posts are now going to change thus breaking all existing links to your blog. However, if you feel you must, these instructions will show you how:
If you do have existing posts you now need to enter the database and update all links within the blog, manually.
mysqldump -u username -p wordpress >~/wordpressbackup.sql
This will generate a file called wordpressbackup.sql in your home directory
<WORK IN PROGRESS!>